Search results for " shale"
showing 10 items of 37 documents
1D Compression Behaviour of Opalinus Clay
2017
One of the main concerns related to tunnel excavations, drilling operations and wellbore stability in shales is the generation of excess pore water pressure due to changes in mechanical stress; therefore the consolidation of shales is a fundamental process that must be considered. This paper presents a compre- hensive methodology for analysing the compression and consolidation behaviour of shales. An apparatus to perform high-pressure oedometric tests is presented and an analytical method is introduced to analyse the shale consolidation behaviour, which allows information to be gathered on the coeffi cient of consolidation, stiffness, poroelastic properties, and permeability of the tested m…
Zirconium–hafnium and rare earth element signatures discriminating the effect of atmospheric fallout from hydrothermal input in volcanic lake water
2016
The geochemical behaviour of Rare Earth Elements, Zr and Hf was investigated in the thermal waters of Nevado del Ruiz volcano system. A wide range of pH, between 1.0 and 8.8, characterizes these fluids. The acidicwaters are sulphate dominatedwith different Cl/SO4 ratios. The important role of the pH and the ionic complexes for the distribution of REE, Zr a nd Hf in the aqueous phase was evidenced. The pH rules the precipitation of authigenic Fe and Al oxyhydroxides producing changes in REE, Zr, Hf amounts and strong anomalies of Cerium. The precipitation of alunite and jarosite removes LREE from the solution, changing the REE distribution in acidic waters. Y-Ho and Zr-Hf (twin pairs) have a…
Students' field research extends knowledge of origin of a UNESCO World Heritage site in Germany
2003
In 1992, as part of field-based course work with the Earth science department of the Universitat Minz, students began to investigate the structures of oil shale basins located in the Sprendlinger Horst, a horst-type block forming the northeastern shoulder of the Tertiary Upper Rhine Graben in southwestern Germany (figure 1). The Sprendlinger Horst is mainly built up by Hercynian or pre-Hercynian basement, Permian sediments, and volcanic rocks, as well as by several Tertiary alkali basalts and rare Cretaceous trachytes. In 1992, it was unknown whether the oil shale basins were of tectonic, volcanic, or even of impact origin.
Bradoriid Arthropods from the Lower-Middle Cambrian of Scania, Sweden
2008
Three species of bradoriid arthropods from the lower to middle Cambrian transitional interval of Scania, southern Sweden, are described and illustrated: Beyrichona tinea from the top of the traditional lower Cambrian (Gislov Formation; Ornamentaspis? linnarssoni Zone), and Hipponicharion eos and Alutella sp. from the basal portion of the traditional middle Cambrian (lowermost part of the Alum Shale Formation). The bradoriid fauna compares most closely with others previously described from western and eastern Avalonia (New Brunswick and England). The record of B. tinea suggests a correlation between the “Protolenus Zone” (Hupeolenus Zone) of western Avalonia and the O.? linnarssoni Zone of S…
Sponges (Porifera) as living metazoan witnesses from the Neoproterozoic: biomineralization and the concept of their evolutionary success
2010
Terra Nova, 22, 1–11, 2010 Abstract The emergence of the Metazoa can be dated back to the Neoproterozoic Era which comprises the Cryogenian Period during which two major glaciations occurred, the Sturtian and the Varanger-Marinoan. At that time, the phylum Porifera (sponges) evolved as the first animals and developed a hard skeleton. The two classes of siliceous sponges, the Hexactinellida and the Demospongiae, are already provided with the major genetic repertoire and gene regulatory networks that also exist in modern multicellular animals. Besides these metazoan innovations, the siliceous sponges display one autapomorphic character, silicatein, an enzyme which mediates bio-silica formatio…
One-dimensional compression and consolidation of shales
2016
This paper presents a comprehensive methodology for analysing the compression and consolidation behaviour of shales. An apparatus was designed to perform oedometric high-pressure tests by applying a maximum vertical total stress of 100 MPa and simultaneously controlling the pore water pressure of the specimen. An analytical method was formulated to analyse the shale consolidation behaviour, which allows information to be gathered on the coefficient of consolidation, stiffness, poroelastic properties, secondary compression and permeability of the tested material as a function of the applied stress conditions. Results obtained on Opalinus Clay shale using the developed methodology are present…
Cr(VI)/Cr(III) and As(V)/As(III) Ratio Assessments in Jordanian Spent Oil Shale Produced by Aerobic Combustion and Anaerobic Pyrolysis
2011
With the increase in the awareness of the public in the environmental impact of oil shale utilization, it is of interest to reveal the mobility of potentially toxic trace elements in spent oil shale. Therefore, the Cr and As oxidation state in a representative Jordanian oil shale sample from the El-Lajjoun area were investigated upon different lab-scale furnace treatments. The anaerobic pyrolysis was performed in a retort flushed by nitrogen gas at temperatures in between 600 and 800 °C (pyrolytic oil shale, POS). The aerobic combustion was simply performed in porcelain cups heated in a muffle furnace for 4 h at temperatures in between 700 and 1000 °C (burned oil shale, BOS). The high loss-…
Discussion on “Experimental Deformation of Opalinus Clay at Elevated Temperature and Pressure Conditions: Mechanical Properties and the Influence of …
2021
AbstractThe testing procedure and results on saturated samples of Opalinus Clay in the work of Schuster et al. (Rock Mech Rock Eng https://doi.org/10.1007/s00603-021-02474-3, 2021) were conducted and presented using strain rates two to four orders of magnitudes higher than the rates needed to allow pore pressure equilibrium in the material, both in drained and undrained conditions. This leads to an erroneous estimation of the mechanical properties in saturated conditions. We discuss this aspect in the context of shale testing. We also discuss the effect of drying-induced fissuring on the mechanical properties of geomaterials tested in dry conditions.
Separation and identification of petroporphyrins extracted from the oil shales of Tarfaya: geochemical study
2002
Abstract Vanadyl and nickel porphyrins were isolated from the oil shales of Tarfaya (Morocco) by extraction followed by column chromatography. The ratios and characteristics of these porphyrin complexes were essentially obtained on the basis of UV–visible and mass spectrometry data. Geochemical information could be drawn from these data. The nature and the contents of the metals coordinated and non-coordinated to porphyrin systems were also determined in this study.
Rhenium‑osmium geochronology of the Toarcian Posidonia Shale, SW Germany
2019
Abstract Black shale samples from sedimentary layers below and between the Unterer Stein, Oberer Stein, Inoceramus Bank, and Nagelkalk horizons from the Dormettingen quarry, SW Germany were analysed for their Re and Os isotope composition and content. The ~12-m-thick sedimentary sequence of the Posidonia Shale Formation, composed of multiple layers of black shale and intercalated limestone beds, was deposited during the Early Jurassic (Toarcian), a time during which black shale sedimentation was ubiquitous in Western Europe during a widespread oceanic anoxic event. Both the marl and shale layers beneath the black shales and adjacent to the Oberer Stein limestone layer show signs of bioturba…